K. Martens, T. Funck, S. Kempter, E.-M. Roller, T. Liedl, B.M. Blaschke, P. Knecht, J.A. Garrido, B. Zhang and H. Kitzerow, Small 12 (12), 1658-1666 (2016)
Composites of DNA origami nanostructures dispersed in a lyotropic chromonic liquid crystal are studied by polarizing optical microscopy. The homogeneous aqueous dispersions can be uniformly aligned by confinement between two glass substrates, either parallel to the substrates owing to uniaxial rubbing or perpendicular to the substrates using ozonized graphene layers. These opportunities of uniform alignment may pave the way for tailored anisometric plasmonic DNA nanostructures to photonic materials. In addition, a decorated texture with nonuniform orientation is observed on substrates coated with pristine graphene. When the water is allowed to evaporate slowly, microscopic crystal needles appear, which are aligned along the local orientation of the director. This decoration method can be used for studying the local orientational order and the defects in chromonic liquid crystals.
© 2016 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.